著者
Shoko Suzuki Ryota Sakamoto Hiroshi Nishihara
出版者
(社)日本化学会
雑誌
Chemistry Letters (ISSN:03667022)
巻号頁・発行日
vol.42, no.1, pp.17-18, 2013-01-05 (Released:2012-12-22)
参考文献数
23
被引用文献数
1

[Ru(tpy)(picSO)]BF4 (tpy: 2,2′:6′,2′′-terpyridine, picSO: 6-[(methylsulfinyl)methyl]picolinate) undergoes profound linkage isomerization behavior between stable S-bound and metastable O-bound isomers. S-[RuII(tpy)(picSO)]BF4 experiences photoisomerization to O-[RuII(tpy)(picSO)]BF4 upon irradiation with 436 nm light, whereas the back reaction is triggered with 546 nm light. Electrochemical linkage isomerization also takes place.

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西原先生 > Two-way Linkage Photoisomerization of [Ru(2,2′:6′,2′′-terpyridine)(6-{(methylsulfinyl)methyl}picolinate)]BF4 https://t.co/ewbZLXO2

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