Spontaneous vapor explosion can occur when a layer of the high temperature molten material lies on the water pool or on the moisture floor. This is so-called base-triggered vapor explosion. The base-triggered vapor explosion is supposed to occur in the case of a severe accident in various industrial facilities. It is very important to clarify the occurrence condition and possibility of the base-triggered vapor explosion from the viewpoints of the prediction and the prevention of the vapor explosion. In order to evaluate the occurrence conditions and to clarify the micro-mechanism of the base-triggered vapor explosion, the experimental apparatus to observe the base-triggered vapor explosion from the bottom of the floor to above is designed and constructed. The experiments using U-Alloy95 as a simulant material are conducted. Consequently, the microscopic behavior at the interface between the molten material and water can be observed in detail with this experimental apparatus. The interfacial behavior of the molten material is quantitatively evaluated by the PIV analysis and the digital auto-colrrelation method with the experimental results. The blowout velocity of the molten material at vapor explosion is evaluated from the visual data obtained on the experiment. The generated pressure at the vapor explosion is estimated by using the blowout velocity. In addition, occurrence condition of the base-triggered vapor explosion is evaluated with the thermal interaction zone (TIZ) theory.