著者

青木 真也

出版者

法政大学大学院理工学・工学研究科

雑誌

法政大学大学院紀要. 理工学・工学研究科編 (ISSN:21879923)

巻号頁・発行日

vol.58, 2017-03-31

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Polystyrene block copolymers containing triethoxysilyl (TES) groups were synthesized by a living anionic polymerization and the subsequent functional group transformation reactions. Then thin polymer films were applied for the reaction with organic acid to form Si-O bonds at the film surface. Surfaceconcentration of Si was confirmed by X-ray photoelectron spectroscopy (XPS) measurement for the resulting polymer film. In addition, contact angle of water droplet for the film increased after acid treatment.These results clearly showed that the polysiloxane substrate was prepared at the outer most surface by treatment with organic acid.Key Words : living anionic polymerization, triethoxysilyl group, surface characterization, block copolymer