著者
浅岡 裕史 小川 りえ 林 秀考 岸本 昭
出版者
公益社団法人日本セラミックス協会
雑誌
Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌) (ISSN:09145400)
巻号頁・発行日
vol.114, no.1332, pp.719-721, 2006
被引用文献数
8

Na&beta;-alumina is a two-dimensional ionic conductor in which insulating spinel layers separate conducting planes of Na<sup>+</sup> ions. Na&beta;-alumina ceramics is expected to be used as solid electrolytes because it is strong ionic conductor and mechanically reliable. Therefore, we prepared <i>c</i>-plane-oriented Na&beta;-alumina ceramics from three aluminum sources using a hot-pressing method and evaluated their ionic conductivity and mechanical strength. In all samples, the ionic conductivity perpendicular to the pressing direction was ten times greater than in the parallel direction. The mechanical strength parallel to the pressing direction was 1.5 times larger than that in the perpendicular direction. The samples made from a mixture of 50 mol% platelike gibbsite and 50 mol% spherical alumina showed the maximum preferential orientation with favorable relative density.<br>