- 著者
- 肥塚 美千代 林 教行 鎌下 知子 末宗 洋 酒井 浄
- 出版者
- The Pharmaceutical Society of Japan
- 雑誌
- Chemical and Pharmaceutical Bulletin (ISSN:00092363)
- 巻号頁・発行日
- vol.36, no.4, pp.1550-1553, 1988-04-25 (Released:2008-03-31)
- 参考文献数
- 10
- 被引用文献数
- 13 14
2, 6-Dioxabicyclo[3.3.0]octan-3, 7-dione seems to be a promising compound for the synthesis of natural products such as epoxyeicosatrienoic acid, laurediol, and eldanolide. This compound, consisting of two γ-lactones, could be prepared by double lactonization of the silver salt of trans-3-hexenedioic acid using iodine. Starting with this bis-lactone, (±)-eldanoide could by synthesized in a stereocontrolled manner.
- 著者
- 末宗 洋 林 教行 舟越 和久 秋田 弘幸 大石 武 酒井 浄
- 出版者
- The Pharmaceutical Society of Japan
- 雑誌
- Chemical and Pharmaceutical Bulletin (ISSN:00092363)
- 巻号頁・発行日
- vol.33, no.5, pp.2168-2170, 1985-05-25 (Released:2008-03-31)
- 参考文献数
- 12
- 被引用文献数
- 24 29
(S)-13-Hydroxy-9Z, 11E-octadecadienoic acid, a defensive substance in rice, was synthesized with high enantioselectivity by the reduction of the corresponding ketone with yeasts.