- 著者
- 枡井 雅一郎 原 晴次郎 上嶋 孝博 川口 哲央 尾崎 茂子
- 出版者
- 公益社団法人日本薬学会
- 雑誌
- Chemical and Pharmaceutical Bulletin (ISSN:00092363)
- 巻号頁・発行日
- vol.31, no.11, pp.4209-4211, 1983-11-25 (Released:2008-03-31)
- 参考文献数
- 9
- 被引用文献数
- 12 61
Benzylic, allylic carbons and the carbon α to hetero atoms are electrochemically oxidized to the corresponding carbonyl group in the presence of N-hydroxyphthalimide under mild conditions.
- 著者
- 枡井 雅一郎 細見 克子 土田 圭一 尾崎 茂子
- 出版者
- 公益社団法人日本薬学会
- 雑誌
- Chemical and Pharmaceutical Bulletin (ISSN:00092363)
- 巻号頁・発行日
- vol.33, no.11, pp.4798-4802, 1985-11-25 (Released:2008-03-31)
- 参考文献数
- 32
- 被引用文献数
- 15 46
Electrochemical oxidation of olefins using N-hydroxyphthalimide as a mediator was studied. Allylic methylene and allylic methine groups were oxidized to give the corresponding enones, while allylic methyl groups were not readily oxidized except for those of 2, 3-dimethyl-2-butene. The product distribution was similar to that observed in free radical autoxidation of olefins. A possible mechanism of the oxidation is proposed.