著者
枡井 雅一郎 原 晴次郎 上嶋 孝博 川口 哲央 尾崎 茂子
出版者
公益社団法人日本薬学会
雑誌
Chemical and Pharmaceutical Bulletin (ISSN:00092363)
巻号頁・発行日
vol.31, no.11, pp.4209-4211, 1983-11-25 (Released:2008-03-31)
参考文献数
9
被引用文献数
12 61

Benzylic, allylic carbons and the carbon α to hetero atoms are electrochemically oxidized to the corresponding carbonyl group in the presence of N-hydroxyphthalimide under mild conditions.
著者
枡井 雅一郎 細見 克子 土田 圭一 尾崎 茂子
出版者
公益社団法人日本薬学会
雑誌
Chemical and Pharmaceutical Bulletin (ISSN:00092363)
巻号頁・発行日
vol.33, no.11, pp.4798-4802, 1985-11-25 (Released:2008-03-31)
参考文献数
32
被引用文献数
15 46

Electrochemical oxidation of olefins using N-hydroxyphthalimide as a mediator was studied. Allylic methylene and allylic methine groups were oxidized to give the corresponding enones, while allylic methyl groups were not readily oxidized except for those of 2, 3-dimethyl-2-butene. The product distribution was similar to that observed in free radical autoxidation of olefins. A possible mechanism of the oxidation is proposed.