- 著者
- Izumi Minoru Fukase Koichi Kusumoto Shoichi
- 出版者
- 社団法人日本農芸化学会
- 雑誌
- Bioscience, biotechnology, and biochemistry (ISSN:09168451)
- 巻号頁・発行日
- vol.66, no.1, pp.211-214, 2002-01-23
- 被引用文献数
- 1 26
Practical Fischer glycosidation was effected at room temperature or 60℃ by using 5 to 10 equiv. of TMSCl. The anomeric propargyl group formed by this method was found to be a versatile new protecting group, being stable in neat TFA but readily cleaved by treatment with Co_2(CO)_8 and TFA in CH_2Cl_2 via the formation of an alkyne-Co complex.