- 著者
-
Katsuhito TAKEI
Nobuyuki SERIZAWA
Tokujiro NISHIKIORI
Yasuhiko ITO
- 出版者
- The Electrochemical Society of Japan
- 雑誌
- Electrochemistry (ISSN:13443542)
- 巻号頁・発行日
- vol.86, no.2, pp.35-37, 2018-03-05 (Released:2018-03-05)
- 参考文献数
- 12
The cathodic reduction of nitrogen (N2) gas in molten chloride was investigated using a porous nickel (Ni) electrode. A LiCl-KCl-CsCl melt containing cathodically formed nitride ion (N3−) was sampled from an electrolytic bath and analyzed quantitatively by ion chromatography. The current efficiency of the cathodic reaction calculated from the ratio of quantity of the produced N3− was approximately 78% on average. The main reason why the measured efficiency did not reach 100% is considered as the amount of N3− increased more in the pores of the gas electrode than in the bulk of the electrolytic bath.