著者

Reboul Julien Furukawa Shuhei Horike Nao Tsotsalas Manuel Hirai Kenji Uehara Hiromitsu Kondo Mio Louvain Nicolas Sakata Osami Kitagawa Susumu

出版者

Nature Publishing Group

雑誌

Nature materials (ISSN:14761122)

巻号頁・発行日

vol.11, no.8, pp.717-723, 2012-06-24

被引用文献数

352 26

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化石化を逆転させ、多孔性メゾ構造体の形をデザイン : 高速分離でバイオエタノール精製などの効率化へ.京都大学プレスリリース.2012-06-25.

著者

Takashima Yohei Martínez Virginia Martínez Furukawa Shuhei Kondo Mio Shimomura Satoru Uehara Hiromitsu Nakahama Masashi Sugimoto Kunihisa Kitagawa Susumu

出版者

Nature Publishing Group

雑誌

Nature communications (ISSN:20411723)

巻号頁・発行日

vol.2, no.1, 2011-01-25

被引用文献数

712

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「ちえのわ」型ナノ細孔を用いたセンサー開発に成功: 動き、捕まえ、光って知らせるナノ多孔体. 京都大学プレスリリース. 2011-01-26.Chemosensors detect a single target molecule from among several molecules, but cannot differentiate targets from one another. In this study, we report a molecular decoding strategy in which a single host domain accommodates a class of molecules and distinguishes between them with a corresponding readout. We synthesized the decoding host by embedding naphthalenediimide into the scaffold of an entangled porous framework that exhibited structural dynamics due to the dislocation of two chemically non-interconnected frameworks. An intense turn-on emission was observed on incorporation of a class of aromatic compounds, and the resulting luminescent colour was dependent on the chemical substituent of the aromatic guest. This unprecedented chemoresponsive, multicolour luminescence originates from an enhanced naphthalenediimide-aromatic guest interaction because of the induced-fit structural transformation of the entangled framework. We demonstrate that the cooperative structural transition in mesoscopic crystal domains results in a nonlinear sensor response to the guest concentration.

著者

Takashima Yohei Martínez Virginia Martínez Furukawa Shuhei Kondo Mio Shimomura Satoru Uehara Hiromitsu Nakahama Masashi Sugimoto Kunihisa Kitagawa Susumu

出版者

Nature Publishing Group

雑誌

Nature communications (ISSN:20411723)

巻号頁・発行日

vol.2, no.1, 2011-01-25

被引用文献数

712

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「ちえのわ」型ナノ細孔を用いたセンサー開発に成功: 動き、捕まえ、光って知らせるナノ多孔体. 京都大学プレスリリース. 2011-01-26.