著者
Kentaro Nakamura Shinsuke Kawagucci Kazuya Kitada Hidenori Kumagai Ken Takai Kyoko Okino
出版者
GEOCHEMICAL SOCIETY OF JAPAN
雑誌
GEOCHEMICAL JOURNAL (ISSN:00167002)
巻号頁・発行日
vol.49, no.6, pp.579-596, 2015-11-26 (Released:2015-12-05)
参考文献数
40
被引用文献数
37 61

Polymetallic sulfides deposited in seafloor hydrothermal vents have recently attracted attention as potential deep-sea mineral resources for base, rare, and precious metals such as Cu, Zn, Pb, In, Ga, Ge, Au, and Ag. For future exploitation of this type of deep-sea mineral resources, development of effective methods for exploring seafloor hydrothermal activity is a key to provide the most promising list of fields. However, conventional exploration methods are likely laborious and time-consuming, and a more efficient methods for exploration of seafloor hydrothermal vents are to be further developed. In the last decade, water column observation using multibeam echo souder (MBES) systems have become successfully applied to exploration of seafloor hydrothermal vents. In 2013 and 2014, we conducted extensive water column surveys using MBES systems in the mid-Okinawa Trough. During the surveys, we detected 10 hydrothermal vent sites, including previously known sites, belonging to four relatively large hydrothermal vent fields, located at the Izena Hole, Iheya North Knoll, Iheya Small Ridge, and a seamount 15 km northwest of the Izena Hole. All of the hydrothermal vent sites are in groups of 2–3 vent sites belonging to a hydrothermal field. Morphological features of the acoustic water column anomalies (rising vertically up to ~1000 m from the seafloor without a significant change of width) implied that the acoustic water column anomalies were not caused directly by hydrothermal vent fluid flows. The depth of the top of the acoustic water column anomalies (~500 m) corresponded rather well to the depth of the CO2 phase transition from liquid/clathrate-hydrate to vapor. This suggests that the acoustic water column anomalies are attributed to water mass including dense liquid CO2 droplets with clathrate-hydrate crusts, which are originally derived from the seafloor hydrothermal fluid discharges.
著者
Akihiro Tamura Takuya Sagawa Kyoko Okino Tomoaki Morishita
出版者
GEOCHEMICAL SOCIETY OF JAPAN
雑誌
GEOCHEMICAL JOURNAL (ISSN:00167002)
巻号頁・発行日
pp.GJ22020, (Released:2022-11-29)
被引用文献数
1

The whole-rock trace-element compositions of igneous rocks provide primary geochemical information about their petrogenesis. Such compositions can be determined by LA–ICP–MS analysis of fused-glass samples as well as the conventional solution ICP–MS method. However, in contrast to basalt and andesite, the fused-glass method is not suitable for Si-rich rocks (granite and rhyolite) due to the difficulty of making homogeneous glasses. To extend the method to Si-rich rocks, we adopted an MgO dilution process to prepare fused glasses and evaluated the technique by analysis of granite and rhyolite reference materials. Dilution of 30 mg of powdered samples with 10 mg MgO facilitated the preparation of homogeneous fused-glass samples of felsic rocks. LA–ICP–MS analyses indicate that the fused glass is homogeneous in the contents of most incompatible elements considered in igneous petrology. The glass enables the analysis of these elements in felsic rocks within 20% deviation from reference data. The sample data are consistent with reference values for rhyolite although Zr and Hf data deviate significantly (by ~40%) from reference values for granitic rocks.