著者
Caglioti Luciano Hajdu Csongor Holczknecht Orsolya Zekany Laszlo Zucchi Claudia Micskei Karoly Palyi Gyula
出版者
文部省科学研究費総合研究(B)「原始地球上における生命の起源に関する研究」班
雑誌
Viva origino (ISSN:09104003)
巻号頁・発行日
vol.34, no.2, pp.62-80, 2006
参考文献数
132

The traditional concept of racemates means an exactly 1:1 mixture of two enantiomeric molecules. Modern analytical and catalytic/preparative discoveries, first of all the Soai-reaction, make necessary a re-evaluation of this concept. The most important aspect of such a revision is the definition of the amount of an excess of one or of the other enantiomer, originating from statistical fluctuation, which can still be "tolerated" when a substance is defined as racemate. The present paper discusses the statistical view of racemates and some related problems.