著者

Hiroki ITO Akira MIURA Yosuke GOTO Yoshikazu MIZUGUCHI Chikako MORIYOSHI Yoshihiro KUROIWA Nataly Carolina ROSERO-NAVARRO Kiyoharu TADANAGA

出版者

The Ceramic Society of Japan

雑誌

Journal of the Ceramic Society of Japan (ISSN:18820743)

巻号頁・発行日

vol.129, no.5, pp.249-253, 2021-05-01 (Released:2021-05-01)

参考文献数

38

被引用文献数

1

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The magnetic and electronic properties of CeOInS2 and their influence on phase transition were analyzed in this study. High-temperature XRD measurements of CeOInS2 revealed that orthorhombic CeOInS2 transformed into tetragonal CeOInS2 at a high temperature of 636 K. The transport properties of CeOInS2 showed semiconducting behavior, with a larger temperature dependence of electronic resistivity in the tetragonal phase compared to that in the orthorhombic phase. Unlike structurally similar Ce(O,F)BiS2 superconductors that show long-range magnetic ordering, CeOInS2 neither exhibited superconductive transition nor long-range magnetic ordering at temperatures between 2 and 300 K.

著者

Ryosuke NAKAZATO Keeko MATSUMOTO Noboru YAMAGUCHI Margherita CAVALLO Valentina CROCELLÀ Francesca BONINO Matthias QUINTELIER Joke HADERMANN Nataly Carolina ROSERO-NAVARRO Akira MIURA Kiyoharu TADANAGA

出版者

The Electrochemical Society of Japan

雑誌

Electrochemistry (ISSN:13443542)

巻号頁・発行日

vol.91, no.9, pp.097003, 2023-09-26 (Released:2023-09-26)

参考文献数

49

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Carbon dioxide electrochemical reduction (CO2ER) has attracted considerable attention as a technology to recycle CO2 into raw materials for chemicals using renewable energies. We recently found that Zn-Al layered double hydroxides (Zn-Al LDH) have the CO-forming CO2ER activity. However, the activity was only evaluated by using the liquid-phase CO2ER. In this study, Ni-Al and Ni-Fe LDHs as well as Zn-Al LDH were synthesized using a facile coprecipitation process and the gas-phase CO2ER with the LDH-loaded gas-diffusion electrode (GDE) was examined. The products were characterized by XRD, STEM-EDX, BF-TEM and ATR-IR spectroscopy. In the ATR-IR results, the interaction of CO2 with Zn-Al LDH showed a different carbonates evolution with respect to other LDHs, suggesting a different electrocatalytic activity. The LDH-loaded GDE was prepared by simple drop-casting of a catalyst ink onto carbon paper. For gas-phase CO2ER, only Zn-Al LDH exhibited the CO2ER activity for carbon monoxide (CO) formation. By using different potassium salt electrolytes affording neutral to strongly basic conditions, such as KCl, KHCO3 and KOH, the gas-phase CO2ER with Zn-Al LDH-loaded GDE showed 1.3 to 2.1 times higher partial current density for CO formation than the liquid-phase CO2ER.