著者

Chinatsu YAMADA Tatsuki TSUJIMORI Qing CHANG Jun–Ichi KIMURA

出版者

Japan Association of Mineralogical Sciences

雑誌

Journal of Mineralogical and Petrological Sciences (ISSN:13456296)

巻号頁・発行日

vol.114, no.6, pp.290-295, 2019 (Released:2020-01-22)

参考文献数

34

被引用文献数

6

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The antigorite–grade serpentinite and Late Paleozoic high–pressure schists are main components of a serpentinite–matrix mélange in the Itoigawa–Omi area, Hida–Gaien Belt, Japan. Based on the petrologic characteristics of the high–pressure schists, the mélange is divided into two units, namely an ‘eclogitic unit’ and a ‘non–eclogitic unit’. Our preliminary in–situ boron isotope analyses of five serpentinites using a laser–ablation multiple–collector inductively–coupled–plasma mass spectrometry (LA–MC–ICPMS) found a systematic difference of boron isotopic trends among the two units in the same mélange. The ‘eclogitic unit’ serpentinites from Yunotani and Kotagi–gawa are characterized by lower δ11B value (mostly lower than +10‰), whereas the non–eclogitic unit serpentinite from Omi–gawa is higher than +10‰. Although the δ11B value of <0‰ was not measured from the eclogitic unit serpentinites, the relatively low δ11B values of <+10‰ might have recorded the signature of fluids released from deep subducted dehydrating slab. In contrast, the non–eclogitic unit serpentinite might have been affected by fluids released from shallower portion. Our new data confirmed the potential sensitivity of the boron isotope signature of serpentinites reflecting variation of high–pressure metamorphism.

著者

Teruyoshi IMAOKA Jun–Ichi KIMURA Qing CHANG Tsuyoshi ISHIKAWA Mariko NAGASHIMA Natsuki TAKESHITA

出版者

Japan Association of Mineralogical Sciences

雑誌

Journal of Mineralogical and Petrological Sciences (ISSN:13456296)

巻号頁・発行日

pp.200721, (Released:2021-02-10)

被引用文献数

4

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We report in situ major and trace element and Li isotope analyses of murakamiite and Li–rich pectolite in an albitite and whole–rock analyses of the albitite and host granite from Iwagi Islet, SW Japan. The albitite forms small bodies that are several tens of centimeters to tens of meters in size, disseminated in a host granite of Late Cretaceous age. The studied murakamiite–bearing albitite contains albite, sugilite, aegirine–augite, quartz, murakamiite–Li–rich pectolite, microcline, katayamalite, and accessory minerals. It shows conspicuous strain–induced textures. The murakamiite and Li–rich pectolite form a solid solution with Li × 100/(Li + Na) atomic ratios ranging from 44.2 to 60.1, and the Na line profiles show a zoning structure in which Na decreases from core to rim. Major and trace element compositions of murakamiite–pectolite normalized to that of albitite indicate the enrichments of some elements, particularly in Mn, Ca, Li, Sr, and REEs, roughly on the same order of magnitude (~ 10 times). The albitite–normalized element concentrations vary systematically with ionic radius of the element; the normalized concentrations of cations with the same valence roughly form a simple convex parabolic curve when plot against the ionic radius. This indicates that the element partitioning of murakamiite and pectolite during metasomatism to form albitite took place under a strong control of crystal structure, quasi–equilibrated with metasomatic fluids and coexisting minerals. The δ7Li values of murakamiite and Li–rich pectolite show a wide range from −9.1 to +0.4‰ (average −2.9‰), and no obvious correlation with Li contents was observed. These δ7Li values should have resulted from hydrothermal fluid–rock interactions at the temperatures of 300–600 °C. The very low δ7Li values down to −9.1‰ may have originated from intra–crystalline Li isotope diffusion, or involvement of deep–seated, Li–Na–enriched subduction–zone fluids with low δ7Li values.