著者
Tabata Kenichi Sasaki Takayuki Yamamoto Yohei
出版者
American Institute of Physics
雑誌
Applied physics letters (ISSN:00036951)
巻号頁・発行日
vol.103, no.4, pp.043301, 2013-07
被引用文献数
9

Organic semiconductor thin films were fabricated by thermal deposition of free-base and metal phthalocyanines under a static magnetic field. A vertical magnetic field enhanced the crystallinity of the edge-on orientation of the phthalocyanine discs, whereas a horizontal magnetic field had a minimal effect on the crystallinity. The major factor for the orientation change is attributed to the diamagnetic anisotropies of π-electrons in the phthalocyanine macrocycles. Field-effect transistors of phthalocyanine films fabricated under a vertical magnetic field exhibited better hole mobilities and on-current values with smaller threshold voltages than those of phthalocyanine films fabricated without a magnetic field.