著者
Matsumoto Takahiro Suzuki Jun-ichi Ohnuma Masato Kanemitsu Yoshihiko Masumoto Yasuaki
出版者
American Physical Society
雑誌
Physical review B (ISSN:10980121)
巻号頁・発行日
vol.63, no.19, pp.195322, 2001-05
被引用文献数
62

The optical absorption spectrum in nanocrystalline silicon (n-Si) was determined from both light transmittance and reflectance measurements. We observed that n-Si has a phonon structure in the optical absorption spectrum. This structure originates from momentum-conserving TO phonon absorption and emission, and provides direct evidence that n-Si is an indirect-band-gap semiconductor with quantum size effects. By using small-angle x-ray scattering to measure the nanocrystal size distribution, we found that the band-gap widening varies as (1/L)1.6 with decreasing nanocrystal diameter L.