著者
Takanori Kotera Masahiro Mikuriya
出版者
The Chemical Society of Japan
雑誌
Chemistry Letters (ISSN:03667022)
巻号頁・発行日
vol.31, no.7, pp.654-655, 2002 (Released:2002-07-05)
参考文献数
18
被引用文献数
4

Thiolato-bridged hexanuclear mixed-valence complex, [CuI3CuII3(apampt)3Cl6] (Hapampt=1-[(3-aminopropyl)amino]-2-methylpropane-2-thiol), has been synthesized and characterized by X-ray crystallography. Spectroscopic data as well as structural features support a localized mixed-valence state. Magnetic susceptibility data show that a strong antiferromagnetic interaction is operating between the CuII ions.