著者
Toshitaka Gamo Harue Masuda Toshiro Yamanaka Kei Okamura Junichiro Ishibashi Eiichiro Nakayama Hajime Obata Kiminori Shitashima Yoshiro Nishio Hiroshi Hasumoto Masaharu Watanabe Kyohiko Mitsuzawa Nobukazu Seama Urumu Tsunogai Fumitaka Kouzuma Yuji Sano
出版者
GEOCHEMICAL SOCIETY OF JAPAN
雑誌
GEOCHEMICAL JOURNAL (ISSN:00167002)
巻号頁・発行日
vol.38, no.6, pp.527-534, 2004-12-20 (Released:2008-04-08)
参考文献数
31
被引用文献数
12 32

This paper reports a series of studies leading to the discovery of a submarine hydrothermal field (called Nakayama Field) at an arc seamount (12°43′N, 143°32′E) in the southernmost part of the Mariana Trough, western Pacific Ocean. We first detected hydrothermal plumes characterized by water column anomalies of temperature, light transmission, Mn, Fe, Al, O2, CH4, and δ13C of CH4 above the summit caldera of the seamount. Then deep-tow camera surveys confirmed the existence of hydrothermal activity inside the caldera, and an ROV dive finally discovered white smoker-type fluid venting associated with vent fauna. A high concentration of aluminum in the plume and white smoker-type emissions imply acidic hydrothermal activity similar to that observed at the DESMOS Caldera in the eastern Manus Basin, Papua New Guinea. Anomalously low δ13C (CH4) of −38‰ of a vent fluid sample compared to other arc hydrothermal systems along the Izu-Bonin and Mariana Arcs suggests an incorporation of biogenic methane based on a subsurface microbial ecosystem.
著者
Naoto Takahata Reika Yokochi Yoshiro Nishio Yuji Sano
出版者
GEOCHEMICAL SOCIETY OF JAPAN
雑誌
GEOCHEMICAL JOURNAL (ISSN:00167002)
巻号頁・発行日
vol.37, no.3, pp.299-310, 2003-06-20 (Released:2008-04-08)
参考文献数
32
被引用文献数
9 15 12

Twenty three gas samples were collected from hot and mineral springs associated with Ontake volcano in central Honshu, Japan from June 1996 to June 2000. The chemical compositions, He, Ar, C and N isotopic ratios were measured using a gas chromatography, noble gas and stable isotope mass spectrometers, respectively. The 3He/4He ratio decreased with increasing distance from the central cone of the volcano to the sampling site, while δ13C value of CO2 increased with the distance. Such trends are consistent with those observed from November 1981 to June 1993 in the literature, suggesting that source of magmatic helium and carbon is located beneath the volcanic cone and they are continuously emitted into surroundings. The δ15N value of N2 increased with the distance while most 40Ar/36Ar ratios were similar to the atmospheric value. Magmatic nitrogen may also be carried by a fluid flowing through the volcanic edifice and diluted by crustal nitrogen. Significant increase of 3He/4He ratio from 1996 to 2000 was observed at the site close to the fault formed by a M6.8 earthquake that occurred in September 1984, which agrees well with the 3He/4He change from November 1981 to June 1993. Anomalous increase of δ13C value was observed at Shirakawa site from June 1993 to June 2000. The change cannot be explained by a simple two-component mixing between magmatic and crustal end-members and may require another model with three end-members, mantle, limestone and sediment.
著者
Rofiqul Umam Masaharu Tanimizu Hitomi Nakamura Yoshiro Nishio Ryo Nakai Naoto Sugimoto Yasunori Mori Yuuki Kobayashi Akane Ito Shigeyuki Wakaki Kazuya Nagaishi Tsuyoshi Ishikawa
出版者
GEOCHEMICAL SOCIETY OF JAPAN
雑誌
GEOCHEMICAL JOURNAL (ISSN:00167002)
巻号頁・発行日
vol.56, no.5, pp.e8-e17, 2022 (Released:2022-10-18)
参考文献数
28
被引用文献数
3

Slab-dehydrated fluid is considered to be involved in island arc magmatism. In this study, Li isotope ratios were determined for deep groundwater samples from the non-volcanic forearc region of SW Japan. The contribution of the slab-dehydrated fluid from the Philippine Sea Plate (PHS) was investigated in the Arima area and the eastern Kii Peninsula area, corresponding to the slab depths of ~60 km and 20–30 km, respectively. In the Arima area, the high-temperature thermal waters with high salinity called the Arima-type fluid were clarified to have low δ7Li values of +1–+3‰. The low δ7Li values with high Li concentrations are thought to be the result of fluid-rock interactions at high temperatures, which is consistent with the characteristics of the slab-dehydrated fluid. On the other hand, the δ7Li values of deep groundwaters in the eastern Kii Peninsula showed a wide range of +2 to +29‰. Several groundwater samples had a similar chemical property to the Arima-type fluid: low δ7Li values, low Cl/Li ratios, and 87Sr/86Sr ratios around 0.708–0.710. They are distributed along the Median Tectonic Line (MTL) and within about 20 km south of the MTL. These results indicate a common supply of slab-dehydrated fluids to the non-volcanic forearc region in SW Japan from PHS along the large faults, and Li isotope ratios will be a useful indicator to detect their contribution.
著者
KYOKO MASUKAWA YOSHIRO NISHIO KEN-ICHIRO HAYASHI
出版者
GEOCHEMICAL SOCIETY OF JAPAN
雑誌
GEOCHEMICAL JOURNAL (ISSN:00167002)
巻号頁・発行日
vol.47, no.3, pp.309-319, 2013-06-20 (Released:2013-11-26)
参考文献数
43
被引用文献数
10

Ore-forming fluid trapped in vein quartz as fluid inclusions from tungsten ore at the Takatori mine was extracted by a crush-leach technique. The trace metal content and isotopic composition (δ7Li and 87Sr/86Sr ratio) of inclusion fluids were measured. Although quartz single crystals can host fluid inclusions associated with different generations, careful selection of analytical samples made it possible to separate the temporal mineralization stages. We succeeded in reconstructing the evolution of the ore-forming fluid from the results of chemical analyses. δ7Li values of the ore-forming fluid were between -2.6 and +7.9‰, gradually increasing in the later stages. The early-stage fluid characterized by low δ7Li values was derived from magma with a meta-sedimentary source (S-type granite). During precipitation of Li-bearing minerals, the δ7Li value of the ore-forming fluid became larger. The initial 87Sr/86Sr ratio of early-stage ore-forming fluid was 0.7202 to 0.7276, suggesting that the fluid responsible for tungsten mineralization was derived from S-type magma, and this magma had a different origin from the granitic rocks widely distributed in the mining area.