著者

Pan Binbin Ma Juanjuan Zhang Xiaobo Li Jinpeng Liu Lin Zhang Dongen Tong Zhiwei

出版者

The Chemical Society of Japan

雑誌

Chemistry Letters (ISSN:03667022)

巻号頁・発行日

2015

被引用文献数

2

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The sandwich-structured nanocomposite of α-ZrP/CoTMPyP [5, 10, 15, 20-tetrakis (N-methylpyridinium-4-yl) porphyrinato cobalt (III)] was fabricated via electrostatic interaction between cobalt porphyrin and α-ZrP nanosheets. The obtained material was used as a modifier on the glassy carbon electrode (GCE) to test the electrocatalytic performance toward oxygen reduction, the results indicated that dioxygen was reduced to H₂O₂ via two-electron transfer.

著者

YUAN Pingfang GUO Kai RUAN Renjun ZHANG Xiaobo LIU Chunjiang

出版者

公益社団法人 化学工学会

雑誌

Journal of Chemical Engineering of Japan (ISSN:00219592)

巻号頁・発行日

vol.49, no.11, pp.951-957, 2016

被引用文献数

1

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<p>Micromixing characteristics of a tubular packed bed reactor with different packings were investigated by adopting the competitive parallel reaction, namely, the Villermaux–Dushman reaction. Better micromixing efficiency was achieved with the tube packed with Winpak® compared to that packed with Mini Ring or Mellapak™ or the empty tube. The segregation index (<i>X</i>_S) decreased as the volumetric flow rate increased, but increased with increasing volumetric flow ratio. Moreover, the micromixing time (<i>t</i>_m) was calculated using an incorporation model based on the experimental data. The minimum <i>t</i>_m value of the tube packed with Winpak® (<i>t</i>_m=1.54 ms) was less than that of the tube packed with Mini Ring (<i>t</i>_m=2.73 ms) or Mellapak™ (<i>t</i>_m=2.14 ms) or the empty tube (<i>t</i>_m=3.79 ms).</p>