著者
小野 健二 松島 知夫 大山 繁 Kenji ONO MATSUSHIMA Tomoo OYAMA Shigeru
雑誌
東北大學選鑛製錬研究所彙報 = Bulletin of the Research Institute of Mineral Dressing and Metallurgy, Tohoku University (ISSN:0040876X)
巻号頁・発行日
vol.23, no.1, pp.25-28, 1967-11-05

For the electrolysis of cobalt the separation of nickel from cobalt pregnant solution by precipitating nickel as nickel Nioxime was studied. The effect of the pH and temperature for the precipitation of nickel was determined. The cobalt electrolyte in the order of the magnitude of the ratio of Ni/Co=n×10^<-4> for electrolysis was obtained by the addition of Nioxime at the pH of 3 to 4 and the temperature of 20° to 80℃.

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Ni(dmg)2(固) ⇔ Ni^2+ + 2dmg^- Ksp=[Ni^2+][dmg^-]^2 Ksp=2.2*10^(-24)、(25℃) Ksp=5.9*10^(-24)、(40℃) 下の pdf ファイルの2ページ目に在る表から抜粋した。 https://tohoku.repo.nii.ac.jp/?action=pages_view_main&active_action= ...

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