著者

Wakamatsu Takamichi Nagao Kazunori Ohmiya Hirohisa Sawamura Masaya

出版者

Beilstein-Institut

雑誌

Beilstein journal of organic chemistry (ISSN:18605397)

巻号頁・発行日

vol.11, pp.2444-2450, 2015-12-04

被引用文献数

8

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A copper-catalyzed conjugate addition of alkylboron compounds (alkyl-9-BBN, prepared by hydroboration of alkenes with 9-BBN-H) to alkynoates to form beta-disubstituted acrylates is reported. The addition occurred in a formal syn-hydroalkylation mode. The syn stereoselectivity was excellent regardless of the substrate structure. A variety of functional groups were compatible with the conjugate addition.