著者

Yasunori Minami Kenta Shimizu Chisato Tsuruoka Takeshi Komiyama Tamejiro Hiyama

出版者

(社)日本化学会

雑誌

Chemistry Letters (ISSN:03667022)

巻号頁・発行日

pp.130919, (Released:2013-10-26)

被引用文献数

20

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Silylation of aryl bromides with disilanes of type [{2-(PGOCH2)C6H4}Me2Si]2 (PG: protecting group) successfully takes place in the presence of a Pd/Ruphos or Davephos/CuI catalytic system to give HOMSi reagents containing various functional groups in good yields. BisHOMSi reagents also were prepared directly from the corresponding arylene dibromides.