著者

大前 雅彦 勝井 五一郎

出版者

公益社団法人 日本ビタミン学会

雑誌

ビタミン (ISSN:0006386X)

巻号頁・発行日

vol.39, no.3, pp.181-189, 1969

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The products of the photolysis of vitamin K_1 in benzene solution were subjected to thin layer chromatograpy using silica gel and chloroform as solvent to give colored spots with Rf of 0 (spot 4), 0.21 (spot 5) and colorless spot with Rf of 0.56 (spot 6) along with other spots. Spot 5 and 6 were elucidated as 5-hydroxy-4-methyl-6,7-benzocoumaran-3-one and phytone, and spot 4 was revealed to be polymer which had the same structure as spot 5.