著者
馬越 啓介 木下 勇 松本 圭司 大井 俊一郎
出版者
公益社団法人 日本化学会
雑誌
日本化学会誌(化学と工業化学) (ISSN:03694577)
巻号頁・発行日
vol.1986, no.11, pp.1517-1520, 1986-11-10 (Released:2011-05-30)
参考文献数
7
被引用文献数
1

The violet bis(2-aminoethyl 2-pyridyl sulfide)cppper(II) perchlorate [1] and blue bis(2-aminoethyl 2-pyridyl sulfoxide)copper(II) perchl3fate [2] were synthesized and have been characterized by means of X-ray crystallography. The Cu(II) atom in 'the cation o[1] is located at the center of symmetry and has a square-planar coordination by 4 N atoms. The S atom in Cu-NH2CH2CH2S-C-N ring lies in the position near to the axial site. The Cu…S distance is 2.832(1) Å and the Cu→S vector intersects the coordination plane at 59.8°. The Cu atom in the centrosymmetric cation of [2] has an elongated octahedral coordination by 4 N (equatorial) and 2 O atoms (axial). The Cu-O distance is 2.301(7) Å.