著者
工藤 恵子 宮原 一元 丸林 信洋 川崎 敏男
出版者
The Pharmaceutical Society of Japan
雑誌
Chemical and Pharmaceutical Bulletin (ISSN:00092363)
巻号頁・発行日
vol.32, no.10, pp.4229-4232, 1984-10-25 (Released:2008-03-31)
参考文献数
16
被引用文献数
6 21

The structure of one of the minor compounds, which coexists only with a 25β (S)-spirostanol glycoside (a steroid saponin) such as I, II, XI and XV, was determined to be the corresponding 22β (S)-0, 25α (S) analog Ia, IIa, XIa and XVa, respectively. Since it was believed that all the natural spirostanol glycosides have the 22α (R)-O configuration, these compounds are worthy of note as the first glycosides of 22β (S)-O-spirostanol so far isolated.