著者

尾中 篤 杉田 啓介 泉 有亮

出版者

公益社団法人 日本化学会

雑誌

日本化学会誌(化学と工業化学) (ISSN:03694577)

巻号頁・発行日

vol.1989, no.3, pp.588-590, 1989-03-10 (Released:2011-05-30)

参考文献数

8

被引用文献数

1

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Regioselective reductions of 2, 3-epoxy-1-alkanol and its derivatives are carried out by use of lithium borohydride supported on calcium ion-exchanged Y-type zeolite.2, 3-Epoxy-substituted ether is found to be reduced at the C-3 position with the above heterogeneous reducing reagent more regioselectively than 2, 3-epoxy-1-alkanol. High regioselection is attributable to the interaction between the organic substrate and the calcium ion in the zeolite since the reducing reagent supported on sodium ion-exchanged zeolite shows low selectivity.