- 著者
- 山田 幸子 石川 正幸 金子 主税
- 出版者
- The Pharmaceutical Society of Japan
- 雑誌
- Chemical and Pharmaceutical Bulletin (ISSN:00092363)
- 巻号頁・発行日
- vol.23, no.11, pp.2818-2834, 1975-11-25 (Released:2008-03-31)
- 被引用文献数
- 12 22
Photolysis of a series of acridine 10-oxides (Ia-Ig) in various solvents is reported. The structures of photo-products were determined by syntheses, chemical transformation to the known compounds, or by direct examination of their spectroscopic data. Based on the structures of photo-products and the solvent effect on the product distribution in these photolyses, a mechanistic rationalization of these photo-reactions is presented. The characteristic features of the photo-rearrangement reactions of acridine 10-oxides are discussed and compared with those of bicyclic and monocyclic azine N-oxides, e, g., quinoline 1-oxides and pyridine 1-oxides.
- 著者
- 落合 英二 金子 主税
- 出版者
- The Pharmaceutical Society of Japan
- 雑誌
- Pharmaceutical Bulletin (ISSN:03699471)
- 巻号頁・発行日
- vol.5, no.1, pp.56-62, 1957-02-20 (Released:2008-02-19)
- 被引用文献数
- 2 10
Durch Nitrierung von Chinolin-N-oxyd mit Benzoylnitrat in Chloroform-bzw. Dioxan-Losung wurde das 3-Nitrochinolin-N-oxyd mit befriedigender Ausbeute erhalten. Pyridin-N-oxyd gibt bei ganz analoger Reaktion das 3-Nitropyridin-N-oxyd trotz sehr schlechter Ausbeute. UV-Absorptionsspektren der isomeren Mononitroderivate des Chinolin-N-oxydes wurden verglichen.