著者

髙坂 泰弘

出版者

一般社団法人 日本ゴム協会

雑誌

日本ゴム協会誌 (ISSN:0029022X)

巻号頁・発行日

vol.91, no.11, pp.400-405, 2018 (Released:2019-04-23)

参考文献数

42

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Conjugate substitution reaction of α-(halomethyl) acrylates that proceeds in addition-elimination (SN2’) mechanism is attractive for polymer chemists, because it undergoes under ambient conditions in quantitative yields to afford α-(substituted methyl) acrylates. In this report, the conjugate substitution reaction is applied to elemental reactions in polymer chemistry, including termination of stereospecific living anionic polymerization, polycondensation, and main chain scission.