著者

Hideaki ISHIDA Makoto HANDA Masahiro MIKURIYA

出版者

(社)日本分析化学会

雑誌

X-ray Structure Analysis Online (ISSN:18833578)

巻号頁・発行日

vol.30, pp.9-10, 2014 (Released:2014-03-21)

参考文献数

6

被引用文献数

6

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The deuterated title compound, aqua adduct of ruthenium 3,4,5-tri(ethoxy-d5)benzoate, diaquatetrakis(μ-3,4,5-tri(ethoxy-d5)benzoato-O,O′)diruthenium(1+) tetrafluoroborate-tetrahydrofuran (1/1), [Ru2{3,4,5-(C2D5O)3CH2CO2}4(H2O)2]BF4·C4H8O, was synthesized. The crystal structure was determined by the single-crystal X-ray diffraction method at 90 K. It crystallizes in the monoclinic space group C2/c with a = 27.243(4)Å, b = 10.4850(15)Å, c = 23.115(3)Å, β = 100.789(3)°, V = 6486.1(16)Å3, Dx = 1.506 g/cm3, and Z = 4. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0460 and 0.1037, respectively, for all 6597 independent reflections. The complex cation has a lantern-like dinuclear ruthenium core with axial water molecules [Ru-Ru 2.2629(8)Å].