著者
Kazuhiro Maruyama Hiroko Yamada Atsuhiro Osuka
出版者
(社)日本化学会
雑誌
Bulletin of the Chemical Society of Japan (ISSN:00092673)
巻号頁・発行日
vol.63, no.12, pp.3462-3466, 1990 (Released:2006-06-05)
参考文献数
19
被引用文献数
5

We applied the Chemically Induced Dynamic Nuclear Polarization (CIDNP) technique to the photochemical reaction of pheophytin a (P1) and 4-methoxyphenol (1) in benzene-d6. The observed CIDNP effects were explained in terms of reversible electron-transfer reactions from 1 to 3(P1)* and from (P1)\ ewdot to (1)\underset.+. The polarized signals of P1 were induced from the in-cage recombination of the triplet radical ion pair.