- 著者
-
Hiroyoshi Sugino
Hidetoshi Kawai
Kenshu Fujiwara
Takanori Suzuki
- 出版者
- (社)日本化学会
- 雑誌
- Chemistry Letters (ISSN:03667022)
- 巻号頁・発行日
- vol.41, no.1, pp.79-81, 2012-01-05 (Released:2011-12-30)
- 参考文献数
- 23
- 被引用文献数
-
8
Condensation reactions of macrocyclic diamines 1 and cyclohexane-1,4-dicarbaldehydes 2 with the substituents at 1,4-positions gave a series of macrocage molecules that can be considered molecular gyroscopes. The gyro-rotational behavior of the cyclohexane rotor is largely affected by the degree of steric requirement of the substituents, and isolation of syn-isomer suggests stepwise motion in the macrocages attached with bulky substituents on the rotor.