著者

Teruaki Mukaiyama Shu Kobayashi Hiromi Uchiro Isamu Shiina

出版者

(社)日本化学会

雑誌

Chemistry Letters (ISSN:03667022)

巻号頁・発行日

vol.19, no.1, pp.129-132, 1990 (Released:2006-05-08)

被引用文献数

31 83 76

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Highly enantioselective aldol reaction of silyl enol ethers with aldehydes is performed by the use of a catalytic amount of chiral diamine coordinated tin(II) triflate according to a slow addition procedure.

著者

Isamu Shiina Keisuke Ono Kenya Nakata

出版者

The Chemical Society of Japan

雑誌

Chemistry Letters (ISSN:03667022)

巻号頁・発行日

vol.40, no.2, pp.147-149, 2011-02-05 (Released:2011-01-08)

参考文献数

18

被引用文献数

48

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A variety of optically active 1-heteroarylalkanols and their esters, which include heteroaromatic moieties, such as 2-furyl, 2-thienyl, 3-thienyl, 2-thiazoyl, 2-benzothiazoyl, and 2-benzoxazoyl groups, are efficiently produced by a novel asymmetric esterification. The transition states that form the desired (R)-esters from the (R)-1-heteroarylalkanols are determined by DFT calculations, and the structural features of these transition states are systematically discussed.