著者
Kazuhiro OKAMOTO Yasushi IMADA Naoki SHIDA Yoshikazu KITANO Mahito ATOBE Kazuhiro CHIBA
出版者
The Electrochemical Society of Japan
雑誌
Electrochemistry (ISSN:13443542)
巻号頁・発行日
vol.91, no.11, pp.112006, 2023-11-28 (Released:2023-11-28)
参考文献数
21
被引用文献数
1

Herein, we report that the 2,7-dimethoxynaphthyl (2,7-DMN) group is a novel electroauxiliary that is readily installed at the N-α position of a carbamate through Friedel–Crafts-type arylation. The resulting N-α C–C bond is easily cleaved through low-potential electrochemical oxidation to give the corresponding iminium cation.