著者
Hideki Sugimoto Reiko Tajima Kazuo Toyota Hiroyuki Miyake Shinobu Itoh
出版者
(社)日本化学会
雑誌
Chemistry Letters (ISSN:03667022)
巻号頁・発行日
vol.40, no.10, pp.1146-1148, 2011-10-05 (Released:2011-09-28)
参考文献数
22
被引用文献数
1

The reaction of bis(dithiolene)sulfidotungsten(IV) complex with elemental sulfur yielded bis(dithiolene)(tetrasulfido)tungsten(IV) complex. A labeling experiment using 34S has indicated that the reaction is reversible and a sulfido(trisulfido)tungsten(VI) species is involved as an intermediate. The reaction represents a model reaction of polysulfide reductase of molybdoenzymes.