著者

Masahiro MIKURIYA Junya YAMAMOTO Kazuya OUCHI Daisuke YOSHIOKA Hidekazu TANAKA Makoto HANDA

出版者

(社)日本分析化学会

雑誌

X-ray Structure Analysis Online (ISSN:18833578)

巻号頁・発行日

vol.29, pp.45-46, 2013 (Released:2013-11-18)

参考文献数

10

被引用文献数

5

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The title compound, a chain adduct of rhodium(II) benzoate with 1,4-diazabicyclo[2.2.2]octane (dabco), catena(tetrakis(μ-benzoato-O,O′)(μ-1,4-diazabicyclo[2.2.2]octane-N,N′)dirhodium(II)-acetonitrile(1/4)), [Rh2(C6H5CO2)4(dabco)]n·4nCH3CN, was isolated. The crystal structure was determined by the single-crystal X-ray diffraction method at 293 K. It crystallizes in the tetragonal space group P4/n with a = 21.3695(18)Å, c = 9.6278(12)Å, V = 4396.6(8)Å3, Dx = 1.468 g/cm3, and Z = 4. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0417 and 0.0825, respectively, for all 5185 independent reflections. The molecule has a linear chain with an alternating arrangement of Rh2(C6H5CO2)4 [Rh-Rh 2.4062(11)Å, 2.4110(11)Å] and dabco. The adsorption property was confirmed for N2 gas with a specific surface area of 387.8 m2 g-1 estimated from an N2 adsorption isotherm.