著者
Megumi Kobayashi Naoki Hayakawa Koichi Nakabayashi Tsukasa Matsuo Daisuke Hashizume Hiroyuki Fueno Kazuyoshi Tanaka Kohei Tamao
出版者
(社)日本化学会
雑誌
Chemistry Letters (ISSN:03667022)
巻号頁・発行日
pp.131043, (Released:2013-12-10)
被引用文献数
23

An air-stable emissive di(1-naphthyl)disilene protected by the bulky Eind groups (Eind = 1,1,3,3,5,5,7,7-octaethyl-s-hydrindacen-4-yl) has been obtained by the reduction of the corresponding dibromosilane (Eind)(1-Naph)SiBr2 with lithium naphthalenide. The X-ray crystallography shows a highly coplanar (E)-1,2-di(1-naphthyl)disilene skeleton, favorable for the efficient π-conjugation involving the Si=Si unit, together with a distinct CH/π interaction between the peri-H atom of the 1-naphthyl groups and the aromatic ring of the perpendicularly-oriented Eind groups.