- 著者
-
Satoru Tsukada
Ryota Sakamoto
Hiroshi Nishihara
- 出版者
- The Chemical Society of Japan
- 雑誌
- Chemistry Letters (ISSN:03667022)
- 巻号頁・発行日
- vol.41, no.4, pp.357-359, 2012-04-05 (Released:2012-03-17)
- 参考文献数
- 43
- 被引用文献数
-
4
[{Cp*Rh(S2C6H4)}2W(CO)2] (Cp*: η5-C5Me5) (1) and [{Cp*Rh(S2C6H4)}(S2C6H4)W(CO)2] (2) were synthesized by the reaction of rhodadithiolene [Cp*Rh(S2C6H4)] with [W(CO)3(py)3], and their crystal structures and physical properties were investigated. The formation mechanism of 2 from 1 was pursued by 1H NMR spectroscopy. 1 reacted with an excess amount of BF3·Et2O to furnish 2, indicating that a Lewis acid assisted the demetalation reaction.