著者
Ryohei Yamakado Shinri Sugimoto Shin-ichi Matsuoka Masato Suzuki Yasuhiro Funahashi Koji Takagi
出版者
(社)日本化学会
雑誌
Chemistry Letters (ISSN:03667022)
巻号頁・発行日
vol.41, no.3, pp.249-251, 2012-03-05 (Released:2012-02-25)
参考文献数
18
被引用文献数
9

m-Calix[3]amide having pyridine on the benzene ring (PyC3A) was synthesized by the cyclization of methyl 3-nonylamino-5-(pyridin-4-yl)benzoate using lithium 1,1,1,3,3,3-hexamethyldisilazide (LiHMDS). The molecular cage 3Pd·2PyC3A was prepared from a 2:3 mixture of PyC3A and [Pd(dppp)(OTf)2] in CDCl3/CD3OD (5/1 in volume). On the other hand, in CDCl3, the formation of a polymeric mixture was confirmed.