著者

Toshiaki INA Yuki ORIKASA Titus MASESE Takayuki NAKAO Atsushi MINESHIGE Koji AMEZAWA Hajime TANIDA Tomoya URUGA Yoshiharu UCHIMOTO

出版者

The Electrochemical Society of Japan

雑誌

Electrochemistry (ISSN:13443542)

巻号頁・発行日

vol.82, no.10, pp.875-879, 2014-10-05 (Released:2014-10-05)

参考文献数

41

被引用文献数

4

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The relationship between the local structure and oxide ionic conduction of Nd2NiO4+δ possessing the K2NiF4 structure was investigated. Various oxygen nonstoichiometry samples of Nd2NiO4+δ prepared with different annealing oxygen partial pressures were examined. The local structure related to oxide ionic conduction was determined by the Nd K-edge extended X-ray absorption fine structure. The oxide ionic conductivity and surface exchange coefficient were estimated using electronic conductivity relaxation methods. The activation energy for the oxide ionic conductivity was found to have a direct correlation to the surface exchange coefficient. The bottleneck size for oxide ion conduction was strongly correlated to the oxide ionic conduction of interstitial oxygen and the oxygen surface exchange rate.

著者

Natee Sirisit Daiki Kido Yuki Wakisaka Hiroko Ariga-Miwa Satoru Takakusagi Kiyotaka Asakura Oki Sekizawa Tomohiro Sakata Tomoya Uruga Yasuhiro Iwasawa

出版者

The Japan Society of Vacuum and Surface Science

雑誌

e-Journal of Surface Science and Nanotechnology (ISSN:13480391)

巻号頁・発行日

vol.16, pp.387-390, 2018-09-01 (Released:2018-09-01)

参考文献数

20

被引用文献数

3

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We have shown a possibility of multi-atom resonant X-ray Raman (MARX-Raman) spectroscopy by measuring the N K-edge loss spectrum of TaN at Ta L3-edge and C K-edge loss spectrum of Er(C5H5)3 at Er L1-edge. When the excitation X-ray energy was tuned to the Ta L3-edge and inelastic scattering spectra were recorded around 400 eV loss corresponding to the N K-edge Raman region, we found a clear enhancement of emission spectrum. The same enhancement was observed in C K-edge Raman region in Er(C5H5)3. These experimental results have indicated the possibility of MARX-Raman phenomenon which may lead to a new in situ and bond-specific XAFS spectroscopy for low Z elements. [DOI: 10.1380/ejssnt.2018.387]