- 著者
- Lan-Chien Huang Tzu-Hsing Ko
- 出版者
- (公社)日本金属学会/(一社)軽金属学会,(一社)資源・素材学会,ナノ学会,(公社)日本金属学会,(一社)日本塑性加工学会,(公社)日本鋳造工学会,日本銅学会,(一社)日本熱処理技術協会,(一社)日本熱電学会,(一社)日本非破壊検査協会,(一社)日本溶射学会,(一社)粉体粉末冶金協会,(公社)腐食防食学会
- 雑誌
- MATERIALS TRANSACTIONS (ISSN:13459678)
- 巻号頁・発行日
- vol.56, no.3, pp.445-449, 2015-03-01 (Released:2015-02-25)
- 参考文献数
- 9
- 被引用文献数
- 1 3
In this study Cu-contaminated soils were chosen as a candidate material for the removal of hydrogen sulfide (H2S) from hot coal gas. Experimental results showed that the H2S was significantly reduced below 10 ppm when the Cu-contaminated soils were reacted with H2S. The optimal removal temperature of H2S was found to be at 923 K in the operating conditions. In addition to Cu species, free Fe oxides in the contaminated soils also performed an active species to react with H2S and enhanced the overall sulfur capacity. Through the XPS analysis, Fe sulfide (FeS) and Cu sulfide (Cu2S) were the major products after removal experiments. Regeneration experimental results also indicated that the Cu-contaminated soils can be regenerated by pass air and thus be reused for many times.