著者
Miyaura Norio Yamada Kinji Suzuki Akira
出版者
Pergamon Press
雑誌
Tetrahedron Letters (ISSN:00404039)
巻号頁・発行日
vol.20, no.36, pp.3437-3440, 1979
被引用文献数
1829

The representative (E)-1-alkenyldisiamylboranes and (E)-1-alkenyl-1,3,2-benzodioxaboroles readily obtainable Image hydroboration of 1-alkynes react with 1-alkenyl halides or 1-alkynyl halides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and base to give corresponding conjugated (E)-dienes or (E)-enynes with high regio- and stereospecificity in good yields, respectively.