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4 0 0 0 OA A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides

著者
Miyaura Norio Yamada Kinji Suzuki Akira
出版者
Pergamon Press
雑誌
Tetrahedron Letters (ISSN:00404039)
巻号頁・発行日
vol.20, no.36, pp.3437-3440, 1979
被引用文献数
1829
The representative (E)-1-alkenyldisiamylboranes and (E)-1-alkenyl-1,3,2-benzodioxaboroles readily obtainable Image hydroboration of 1-alkynes react with 1-alkenyl halides or 1-alkynyl halides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and base to give corresponding conjugated (E)-dienes or (E)-enynes with high regio- and stereospecificity in good yields, respectively.

1 0 0 0 OA Aerobic oxidative dehydrogenations of benzyl alcohols to benzaldehydes by using a cyclometalated ruthenium catalyst

著者
Taketoshi Ayako Beh Xin Ning Kuwabara Junpei Koizumi Take-aki Kanbara Takaki
出版者
Elsevier Ltd.
雑誌
Tetrahedron letters (ISSN:00404039)
巻号頁・発行日
vol.53, no.28, pp.3573-3576, 2012-07
被引用文献数
23
The ruthenium(III) complex bearing phenylpyridine as acyclometalated ligand serves as an efficient catalyst for the aerobicoxidativedehydrogenation of benzylalcohols to the corresponding benzaldehydes under mild conditions and for the one-pot synthesis of benzonitriles from benzylalcohols with ammonia.