著者
Yasuhiro Morisaki Yoshiki Chujo
出版者
(社)日本化学会
雑誌
Chemistry Letters (ISSN:03667022)
巻号頁・発行日
vol.41, no.9, pp.840-846, 2012-09-05 (Released:2012-08-25)
参考文献数
67
被引用文献数
27 5

Incorporation of a [2.2]paracyclophane skeleton into a conjugated polymer main chain affords a polymer comprising stacked π-electron systems. In this article, we describe the synthesis and optical properties of some [2.2]paracyclophane-based polymers on the basis of the results of our resent research. We discuss the role of [2.2]paracyclophane in the polymer backbone, through-space conjugation of the polymer, and the feasibility of using the titled polymers as single molecular wires that allow for unidirectional energy and charge transfer via through-space interactions.