著者

Yoichiro Kuninobu Kazuhiko Takai

出版者

(社)日本化学会

雑誌

Bulletin of the Chemical Society of Japan (ISSN:00092673)

巻号頁・発行日

vol.85, no.6, pp.656-671, 2012-06-15 (Released:2012-06-15)

参考文献数

97

被引用文献数

31

---

Rhenium- or manganese-catalyzed transformations based on the cleavage of inactive bonds, such as carbon–hydrogen and carbon–carbon bonds are discussed. Such transformations are recognized as key methods to realize efficient and powerful reactions. We also reveal novel regio- and/or stereodefined cycloaddition reactions using a rhenium or manganese catalyst. Most of the catalytic activities are typical of rhenium and manganese carbonyl complexes.