著者

青木 孝 アオキ タカシ

出版者

神奈川大学総合理学研究所

雑誌

Science Journal of Kanagawa University (ISSN:18800483)

巻号頁・発行日

vol.30, pp.9-16, 2019-06-30

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Breadcrumbs made from "Denki-Pan" (breads baked using an electrode bread machine invented by Shozo Akutsu) are still on the market. We conducted an experiment to reproduce Denki-Pan, and compared stainless steel and titanium as electrode plate materials. The experiment revealed that the existing technology to cook rice with electrodes ("Denki-Rice") had been applied to Denki-Pan. Thus, Shozo Akutsu had put a two-purpose device into practical use. Electrodes to cook Denki-Rice are placed either parallel or at the bottom of a cooker. We investigated historical factors that influenced the process of materializing this idea.

著者

辻 勇人 金澤 悠紀 江原 雅博 ツジ ハヤト エハラ マサヒロ

出版者

神奈川大学総合理学研究所

雑誌

Science journal of Kanagawa University = 神奈川大学理学誌 (ISSN:18800483)

巻号頁・発行日

vol.29, pp.51-53, 2018

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原著2017年度神奈川大学総合理学研究所共同研究助成論文

著者

辻 勇人 金澤 悠紀 江原 正博 ツジ ハヤト エハラ マサヒロ

出版者

神奈川大学総合理学研究所

雑誌

Science journal of Kanagawa University = 神奈川大学理学誌 (ISSN:18800483)

巻号頁・発行日

vol.31, pp.61-64, 2020

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Geometric optimization of the excited states of n-Si5Me12 and n-Si7Me16 was performed using time-dependent density functional theory calculations to compare their structures and emission properties. It was found that the geometry of n-Si5Me12 changes from alltransoid in the ground state to all-anti in the excited state, whereas that of n-Si7Me16 remains all-transoid in both states. This is related to elongation of the Si-Si bond lengths in the excited state, showing σσ* : those of pentasilane elongate to 2.45-2.49 Å with bond angles up to 141° in the excited state, which facilitates its conformation to relax all-anti by releasing the 1,3-repulsion between the methyl groups. Meanwhile, those of heptasilane (less than 2.434 Å and 125°) do not elongate as much as those of pentasilane, which restrict its conformation similar to that in the ground state. Calculated emission wavelengths and oscillator strengths of these oligosilanes effectively reproduced the experimental data: large and small Stokes shifts in pentasilane and heptasilane, respectively, were estimated in agreement with calculated geometric changes.原著2019年度神奈川大学総合理学研究所共同研究助成論文

著者

十亀 孝維 大和田 正人 金沢 謙一

出版者

神奈川大学総合理学研究所

雑誌

神奈川大学理学誌 (ISSN:18800483)

巻号頁・発行日

vol.20, no.1, pp.89-92, 2009