著者

西林 仁昭

出版者

錯体化学会

雑誌

Bulletin of Japan Society of Coordination Chemistry (ISSN:18826954)

巻号頁・発行日

vol.71, pp.49-55, 2018-05-31 (Released:2018-08-24)

参考文献数

22

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This paper describes our recent progress in catalytic nitrogen fixation by using transition metal-dinitrogen complexes as catalysts. Novel reaction systems for the catalytic transformation of molecular dinitrogen into ammonia and hydrazine undermild reaction conditions have been achieved by the molybdenum-, iron-, cobalt-, and vanadium-dinitrogen complexes as catalysts. New findings presented in this paper may provide a new approach to the development of economical nitrogen fixation in place of energy-consuming Haber-Bosch process.