著者
桂 智男 丹下 慶範
出版者
日本高圧力学会
雑誌
高圧力の科学と技術 (ISSN:0917639X)
巻号頁・発行日
vol.30, no.3, pp.237-249, 2020 (Released:2021-01-29)
参考文献数
13

The Eulerian finite strain of an elastically isotropic body is defined by taking the state after compression as the reference state and expanding the squared length. The second-, third- and fourth-order Birch-Murnaghan equations of state are plainly derived based on the Eulerian finite strain. The key for the plain derivation is no use of differenital or tensor because of isotropic, uniform and finite change in length. For better understanding, the finite strain in the Lagrangian scheme is defined by taking the state before compression as the reference state, and the Lagrange equations of state are derived in this scheme. In this scheme, pressure increases less significantly with compression than the Eulerian scheme. The different Eulerian strains are also defined by expanding the linear and cubed lengths instead of the squared length, and the first- and third-power Eulerian equations of state are derived in these schemes. Fitting of pressure-scale-free data to these equations indicates that the Lagrangian scheme is inappropriate to describe P-V-T relations of MgO, whereas three Eulerian equations of state have equivalent significance, and the Birch-Murnaghan equations of state does not have special meaning compared to the other Eulerian equations of state.

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@Dau60028 第一原理計算界隈では有名です。計算結果をBirch–Murnaghanの式にフィッティングすることにより、平衡格子定数、体積弾性率、体積弾性率の圧力微分の値が得られ、実験と比較できます。ちなみに、Birch–Murnaghanの式には2次、3次、4次があります(もっと高次もあり得る)。 https://t.co/34D3k78ZsA

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