著者

田中 秀和 中林 祐治 新居 正浩 石川 達雄 中山 武典

出版者

一般社団法人 粉体工学会

雑誌

粉体工学会誌 (ISSN:03866157)

巻号頁・発行日

vol.55, no.5, pp.269-274, 2018-05-10 (Released:2018-07-10)

参考文献数

29

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In order to simulate the atmospheric corrosion of tannic acid-coated steels in industrial and coastal districts, artificial steel rust particles of α- and β-FeOOH were synthesized by aerial oxidation of aqueous Fe2+ solutions containing various amounts of tannic acid. Increasing addition amount of tannic acid accelerates the formation of amorphous iron-gallic acid complexes to suppress the generation of FeOOH rust. The crystallization and growth of α-FeOOH particles were inhibited by adding tannic acid, while those of β-FeOOH particles are markedly dependent of addition amount of tannic acid. Accordingly, it can be regarded that the tannic acid eluted from tannic acid-coated steels by atmospheric corrosion strongly affects on the formation of α- and β-FeOOH rust and the effect in coastal area is greater than urban district.