著者

銅金 巌 山近 洋 南井 正好

出版者

The Society of Synthetic Organic Chemistry, Japan

雑誌

有機合成化学協会誌 (ISSN:00379980)

巻号頁・発行日

vol.41, no.10, pp.896-903, 1983 (Released:2009-11-13)

参考文献数

41

被引用文献数

5 7

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The purpose of the present research is to establish new methods in the commercial production of cyclopentenones. Cyclopentenones are very important compounds for fine chemical industry. (agrochemicals, perfumes, pharmaceuticals)The present paper is concerned with syntheses of cyclopentenones through a molecular rearrangement of 2-furylcalbinols, which was discovered by G. Piancatelli. On this reaction, several improvements are achieved from the industrial viewpoints. This method is applied for the syntheses of following compounds.(1) intermediates of pyrethroidal insecticides(2) optical active cyclopentenones(3) jasmones(4)intermediates of prostagrandins(5) norbornadienes …… compounds for the storage of light energy