著者

北嶋 英彦 高橋 俊章 堂下 豊史 毛海 敬

出版者

公益社団法人 日本化学会

雑誌

日本化学会誌(化学と工業化学) (ISSN:03694577)

巻号頁・発行日

vol.1988, no.2, pp.239-242, 1988-02-10 (Released:2011-05-30)

参考文献数

12

被引用文献数

1

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The palladium-catalyzed alkynylation of 4, 6-disubstituted 2-iodo-1, 3, 5-triazines [1] (substituent a, NMe2; b, Ph; c, OMe) with monosubstituted acetylenes [2] (substituent a, Ph; b, COOMe; c, CMe2OH) afforded the corresponding cross-coupling products [3] in moderate yields except for the case of [2 c]. The cross-product [3 ac] reacted with [1 a] to give bis [4, 6-bis(dimethylamino)-1, 3, 5-triazin-2-yl]acetylene.