著者
新森 英之 大須賀 篤弘
出版者
The Society of Synthetic Organic Chemistry, Japan
雑誌
有機合成化学協会誌 (ISSN:00379980)
巻号頁・発行日
vol.57, no.9, pp.749-762, 1999-09-01 (Released:2009-11-16)
参考文献数
64
被引用文献数
7 9

Recent advances in the synthesis of covalently linked multiporphyrin arrays are summarized with particular emphasis on those with well-defined geometries and with novel and interesting properties. Of these, 1) aromatic-group bridged porphyrin arrays have been proved to be useful for defining geometries of the porphyrin arrays without alternation of physical properties of porphyrin subunits, 2) ethynyl-group bridged porphyrin arrays that are relatively easy to make by palladium-catalyzed reactions display significant changes in their optical and electrochemical properties particularly when the ethynyl groups are attached at the meso-positions of porphyrins, and 3) meso-meso linked multiporphyrin arrays are promising in view of their unique optical properties, easy extension to higher oligomers, and relatively high solubility.